Doctor Doom

Summary of Character
Victor von Doom (also known as Doctor Doom) is a fictional character who appears in Marvel Comics publications. Created by Stan Lee and Jack Kirby, the character first appeared in Fantastic Four #5 (July 1962) wearing his trademark metal mask and green cloak. The son of a gypsy witch, Doom is a recurring supervillain, arch enemy of the Fantastic Four, and leader of the fictional nation of Latveria. He is both a genius inventor and a sorcerer, and has served as a primary antagonist and occasional protagonist in the Marvel continuity since his creation. Doom's most famous opponents include the Fantastic Four, Spider-Man, Doctor Strange, the Avengers, the X-Men, Punisher, Blade, Iron Man, and even Silver Surfer.

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Season 1

 * Episode 8 I Love You, Iron Man: Himself as Iron Man's friend.